This is an interesting concept. "Glue is very different than most social network's you've likely used - Glue is entirely browser-based. With Glue there is no destination website, your network lives inside your browser, and is always available as you browse the web. Using some semantic web special sauce, Glue will pop up a small toolbar at the top of the page whenever you land on a site that Glue tracks." Most of the sites are destination sites like site like Amazon, Last.fm, Netflix or Wikipedia, so Glue still focuses, in its own way, on the centralized services. Still, there's some there there.
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